Unraveling Mechanisms in Organic Processes by Natural Mineral and Biological Catalysts
TITLE: Selectivity in Enzymatic Phosphorus Recycling from Biopolymers: Isotope Effect, Reactivity Kinetics, and Molecular Docking with Fungal and Plant Phosphatases –ABSTRACT Among ubiquitous phosphorus (P) reserves in environmental matrices are ribonucleic acid (RNA) and polyphosphate (polyP), which are, respectively, organic
TITLE: Metabolomics analysis of unresolved molecular variability in stoichiometry dynamics of a stream dissolved organic matter –ABSTRACT: Broad molecular classification based on stoichiometric ratio relationships has been used extensively to characterize the chemical diversity of aquatic dissolved organic matter (DOM).
TITLE: Dynamic utilization of low-molecular-weight organic substrates across a microbial growth rate gradient –Aim: Low-molecular-weight organic substances (LMWOSs) are at the nexus between microorganisms, plant roots, detritus, and the soil mineral matrix. Nominal oxidation state of carbon (NOSC) has been
TITLE: Evolution of Oxygen Isotopologues in Phosphate and Pyrophosphate during Enzyme-Catalyzed Isotopic Exchange Reactions –ABSTRACT: Inorganic pyrophosphatase (PPase) is an enzyme that catalyzes the hydrolysis of the phosphoanhydride bond in pyrophosphate (PPi) to release inorganic phosphate (Pi) and simultaneously exchange
TITLE: Lithium isotope behaviour during basalt weathering experiments amended with organic acids –ABSTRACT: Lithium (Li) isotopes are a tracer of silicate weathering processes, but how they react to different components of organic and plant-assisted weathering is poorly known. To examine
TITLE: Strategies of organic phosphorus recycling by soil bacteria: Acquisition, metabolism, and regulation –ABSTRACT: Critical to meeting cellular phosphorus (P) demand, soil bacteria deploy a number of strategies to overcome limitation in inorganic P (Pi) in soils. As a significant
TITLE: Analogous Metabolic Decoupling in Pseudomonas putida and Comamonas testosteroni Implies Energetic Bypass to Facilitate Gluconeogenic Growth –ABSTRACT: Gluconeogenic carbon metabolism is not well understood, especially within the context of flux partitioning between energy generation and biomass production, despite the
TITLE: Quantitative Spectroscopic Analysis of Water Populations in the Hydrated Nanopore Environments of a Natural Montmorillonite –ABSTRACT: Smectite clays are implicated in solute trapping in natural and engineered processes. Here we evaluated 23Na solid-state nuclear magnetic resonance (NMR) and thermogravimetric
TITLE: Effects of Phosphonate Herbicides on the Secretions of Plant-Beneficial Compounds by two Plant Growth-Promoting Soil Bacteria: A Metabolomics Investigation –ABSTRACT: Plant growth-promoting rhizobacteria (PGPR) that colonize plant roots produce a variety of plant-beneficial compounds, including plant-growth regulators, metal-scavenging compounds,
TITLE: Phosphonate Herbicide Interactions with Quartz, Montmorillonite, and Quartz-Enriched Agricultural Soil: Molecular Modeling Simulations and Adsorption-Desorption Experiments –ABSTRACT: Phosphonate-based herbicides are extensively used in agriculture. Glyphosate was long considered immobile in soils due to strong complexation with metal oxides, but